A redox-neutral catechol synthesis

Ubiquitous tyrosinase catalyses the aerobic oxidation of phenols to catechols through the binuclear copper centres. Here, inspired by the Fischer indole synthesis, we report an iridium-catalysed tyrosinase-like approach to catechols, employing an oxyacetamide-directed C–H hydroxylation on phenols. T...

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Detalles Bibliográficos
Autores principales: Wu, Qian, Yan, Dingyuan, Chen, Ying, Wang, Ting, Xiong, Feng, Wei, Wei, Lu, Yi, Sun, Wei-Yin, Li, Jie Jack, Zhao, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290158/
https://www.ncbi.nlm.nih.gov/pubmed/28128196
http://dx.doi.org/10.1038/ncomms14227

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290158/
https://www.ncbi.nlm.nih.gov/pubmed/28128196
http://dx.doi.org/10.1038/ncomms14227

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