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A redox-neutral catechol synthesis
Ubiquitous tyrosinase catalyses the aerobic oxidation of phenols to catechols through the binuclear copper centres. Here, inspired by the Fischer indole synthesis, we report an iridium-catalysed tyrosinase-like approach to catechols, employing an oxyacetamide-directed C–H hydroxylation on phenols. T...
Autores principales: | Wu, Qian, Yan, Dingyuan, Chen, Ying, Wang, Ting, Xiong, Feng, Wei, Wei, Lu, Yi, Sun, Wei-Yin, Li, Jie Jack, Zhao, Jing |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290158/ https://www.ncbi.nlm.nih.gov/pubmed/28128196 http://dx.doi.org/10.1038/ncomms14227 |
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