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Crystal structure of (2,2′-bipyrid­yl)[2,6-bis­(1-butyl-1H-benzimidazol-2-yl)pyridine]­chlorido­iridium(III) tri­fluoro­methane­sulfonate

The title complex compound, [Ir(C(27)H(29)N(5))Cl(C(10)H(8)N(2))](CF(3)SO(3))(2), was synthesized for a study of iridium(III)/periodate redox systems in water. The coordination geometry of the complex can be best described as distorted octa­hedral, with an r.m.s. deviation of 8.8 (8)% from ideal oct...

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Detalles Bibliográficos
Autores principales: Smith, Victoria I., Nozari, Mohammad, Zeller, Matthias, Addison, Anthony W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290549/
https://www.ncbi.nlm.nih.gov/pubmed/28217326
http://dx.doi.org/10.1107/S205698901700010X