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Crystal structure of rubidium methyl­diazo­tate

The title compound, Rb(+)·H(3)CN(2)O(−), has been crystallized in liquid ammonia as a reaction product of the reductive ammonolysis of the natural compound streptozocin. Elemental rubidium was used as reduction agent as it is soluble in liquid ammonia, forming a blue solution. Reductive bond cleavag...

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Detalles Bibliográficos
Autores principales: Grassl, Tobias, Korber, Nikolaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5290556/
https://www.ncbi.nlm.nih.gov/pubmed/28217333
http://dx.doi.org/10.1107/S2056989016020429