Synergistic Photoredox/Nickel Coupling of Acyl Chlorides with Secondary Alkyltrifluoroborates: Dialkyl Ketone Synthesis

[Image: see text] Visible light photoredox/nickel dual catalysis has been employed in the cross-coupling of acyl chlorides with potassium alkyltrifluoroborates. This protocol, based on single-electron-mediated alkyl transfer, circumvents the restriction of using reactive alkylmetallic nucleophiles i...

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Detalles Bibliográficos
Autores principales: Amani, Javad, Molander, Gary A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5295362/
https://www.ncbi.nlm.nih.gov/pubmed/28093913
http://dx.doi.org/10.1021/acs.joc.6b02897

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5295362/
https://www.ncbi.nlm.nih.gov/pubmed/28093913
http://dx.doi.org/10.1021/acs.joc.6b02897

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