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The Cobalt cyclo‐P(4) Sandwich Complex and Its Role in the Formation of Polyphosphorus Compounds
A synthetic approach to the sandwich complex [Cp′′′Co(η(4)‐P(4))] (2) containing a cyclo‐P(4) ligand as an end‐deck was developed. Complex 2 is the missing homologue in the series of first‐row cyclo‐P(n) sandwich complexes, and shows a unique tendency to dimerize in solution to form two isomeric P(8...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5299486/ https://www.ncbi.nlm.nih.gov/pubmed/28078794 http://dx.doi.org/10.1002/anie.201610967 |