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A Monoanionic Arsenide Source: Decarbonylation of the 2‐Arsaethynolate Anion upon Reaction with Bulky Stannylenes
We report fundamental studies on the reactivity of the 2‐arsaethynolate anion (AsCO(−)), a species that has only recently become synthetically accessible. The reaction of AsCO(−) with the bulky stannylene Ter(2)Sn (Ter=2,6‐bis[2,4,6‐trimethylphenyl]phenyl) is described, which leads to the unexpected...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5299489/ https://www.ncbi.nlm.nih.gov/pubmed/27862768 http://dx.doi.org/10.1002/anie.201609309 |