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Engineering catalytic coordination space in a chemically stable Ir-porphyrin MOF with a confinement effect inverting conventional Si–H insertion chemoselectivity
An iridium-porphyrin ligand, Ir(TCPP)Cl (TCPP = tetrakis(4-carboxyphenyl)porphyrin), has been utilized to react with HfCl(4) to generate a stable Ir(iii)-porphyrin metal–organic framework of the formula [(Hf(6)(μ(3)-O)(8)(OH)(2)(H(2)O)(10))(2)(Ir(TCPP)Cl)(3)]·solvents (Ir-PMOF-1(Hf)), which possesse...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5299935/ https://www.ncbi.nlm.nih.gov/pubmed/28451226 http://dx.doi.org/10.1039/c6sc03288e |