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Photo-driven redox-neutral decarboxylative carbon-hydrogen trifluoromethylation of (hetero)arenes with trifluoroacetic acid

Catalytic oxidative C–H bond functionalization reactions that proceed without requiring stoichiometric amounts of external oxidants or pre-functionalized oxidizing reagents could maximize the atom- and step-economy in chemical syntheses. However, such a transformation remains elusive. Here, we repor...

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Detalles Bibliográficos
Autores principales: Lin, Jin, Li, Zhi, Kan, Jian, Huang, Shijun, Su, Weiping, Li, Yadong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5303830/
https://www.ncbi.nlm.nih.gov/pubmed/28165474
http://dx.doi.org/10.1038/ncomms14353