Cargando…
Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin
The uranyl(vi) complex UO(2)Cl(L) of the redox-active, acyclic diimino-dipyrrin anion, L(–) is reported and its reaction with inner- and outer-sphere reductants studied. Voltammetric, EPR-spectroscopic and X-ray crystallographic studies show that chemical reduction by the outer-sphere reagent CoCp(2...
Autores principales: | , , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5304617/ https://www.ncbi.nlm.nih.gov/pubmed/28451154 http://dx.doi.org/10.1039/c6sc02912d |