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Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin

The uranyl(vi) complex UO(2)Cl(L) of the redox-active, acyclic diimino-dipyrrin anion, L(–) is reported and its reaction with inner- and outer-sphere reductants studied. Voltammetric, EPR-spectroscopic and X-ray crystallographic studies show that chemical reduction by the outer-sphere reagent CoCp(2...

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Detalles Bibliográficos
Autores principales:	Pankhurst, James R., Bell, Nicola L., Zegke, Markus, Platts, Lucy N., Lamfsus, Carlos Alvarez, Maron, Laurent, Natrajan, Louise S., Sproules, Stephen, Arnold, Polly L., Love, Jason B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2017
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5304617/ https://www.ncbi.nlm.nih.gov/pubmed/28451154 http://dx.doi.org/10.1039/c6sc02912d

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