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Pyramidalization/twisting of the amide functional group via remote steric congestion triggered by metal coordination
For decades, the planarity of the amide functional group has garnered sustained interest in organic chemistry, enticing chemists to deform its usually characteristic high-fidelity plane. As opposed to the construction of amides that are distorted by imposing rigid covalent bond assemblies, we demons...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5304688/ https://www.ncbi.nlm.nih.gov/pubmed/28451151 http://dx.doi.org/10.1039/c6sc03669d |