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A unique Pd-catalysed Heck arylation as a remote trigger for cyclopropane selective ring-opening
Combining functionalization at a distant position from a reactive site with the creation of several consecutive stereogenic centres, including the formation of a quaternary carbon stereocentre, in acyclic system represents a pinnacle in organic synthesis. Here we report the regioselective Heck aryla...
Autores principales: | Singh, Sukhdev, Bruffaerts, Jeffrey, Vasseur, Alexandre, Marek, Ilan |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5309700/ https://www.ncbi.nlm.nih.gov/pubmed/28169276 http://dx.doi.org/10.1038/ncomms14200 |
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