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Enzyme-Catalyzed Cationic Epoxide Rearrangements in Quinolone Alkaloid Biosynthesis

Epoxides are highly useful synthons and biosynthons in the construction of complex natural products during total synthesis and biosynthesis, respectively. Among enzyme-catalyzed epoxide transformations, a notably missing reaction, compared to the synthetic toolbox, is cationic rearrangement that tak...

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Detalles Bibliográficos
Autores principales: Zou, Yi, Garcia-Borràs, Marc, Tang, Mancheng C., Hirayama, Yuichiro, Li, Dehai H., Li, Li, Watanabe, Kenji, Houk, K. N., Tang, Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5310975/
https://www.ncbi.nlm.nih.gov/pubmed/28114276
http://dx.doi.org/10.1038/nchembio.2283