(13)C ENDOR Spectroscopy of Lipoxygenase–Substrate Complexes Reveals the Structural Basis for C–H Activation by Tunneling

[Image: see text] In enzymatic C–H activation by hydrogen tunneling, reduced barrier width is important for efficient hydrogen wave function overlap during catalysis. For native enzymes displaying nonadiabatic tunneling, the dominant reactive hydrogen donor–acceptor distance (DAD) is typically ca. 2...

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Detalles Bibliográficos
Autores principales: Horitani, Masaki, Offenbacher, Adam R., Carr, Cody A. Marcus, Yu, Tao, Hoeke, Veronika, Cutsail, George E., Hammes-Schiffer, Sharon, Klinman, Judith P., Hoffman, Brian M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5322796/
https://www.ncbi.nlm.nih.gov/pubmed/28121140
http://dx.doi.org/10.1021/jacs.6b11856

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5322796/
https://www.ncbi.nlm.nih.gov/pubmed/28121140
http://dx.doi.org/10.1021/jacs.6b11856

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