Isotope Probing of the UDP‐Apiose/UDP‐Xylose Synthase Reaction: Evidence of a Mechanism via a Coupled Oxidation and Aldol Cleavage

The C‐branched sugar d‐apiose (Api) is essential for plant cell‐wall development. An enzyme‐catalyzed decarboxylation/pyranoside ring‐contraction reaction leads from UDP‐α‐d‐glucuronic acid (UDP‐GlcA) to the Api precursor UDP‐α‐d‐apiose (UDP‐Api). We examined the mechanism of UDP‐Api/UDP‐α‐d‐xylose...

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Detalles Bibliográficos
Autores principales: Eixelsberger, Thomas, Horvat, Doroteja, Gutmann, Alexander, Weber, Hansjörg, Nidetzky, Bernd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5324594/
https://www.ncbi.nlm.nih.gov/pubmed/28102965
http://dx.doi.org/10.1002/anie.201609288

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5324594/
https://www.ncbi.nlm.nih.gov/pubmed/28102965
http://dx.doi.org/10.1002/anie.201609288

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