Cargando…

Isotope Probing of the UDP‐Apiose/UDP‐Xylose Synthase Reaction: Evidence of a Mechanism via a Coupled Oxidation and Aldol Cleavage

The C‐branched sugar d‐apiose (Api) is essential for plant cell‐wall development. An enzyme‐catalyzed decarboxylation/pyranoside ring‐contraction reaction leads from UDP‐α‐d‐glucuronic acid (UDP‐GlcA) to the Api precursor UDP‐α‐d‐apiose (UDP‐Api). We examined the mechanism of UDP‐Api/UDP‐α‐d‐xylose...

Descripción completa

Detalles Bibliográficos
Autores principales:	Eixelsberger, Thomas, Horvat, Doroteja, Gutmann, Alexander, Weber, Hansjörg, Nidetzky, Bernd
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2017
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5324594/ https://www.ncbi.nlm.nih.gov/pubmed/28102965 http://dx.doi.org/10.1002/anie.201609288

Ejemplares similares

Deciphering the enzymatic mechanism of sugar ring contraction in UDP-apiose biosynthesis
por: Savino, Simone, et al.
Publicado: (2019)

Structure and Mechanism of Human UDP-xylose Synthase: EVIDENCE FOR A PROMOTING ROLE OF SUGAR RING DISTORTION IN A THREE-STEP CATALYTIC CONVERSION OF UDP-GLUCURONIC ACID
por: Eixelsberger, Thomas, et al.
Publicado: (2012)

Biosynthesis of UDP-xylose and UDP-arabinose in Sinorhizobium meliloti 1021: first characterization of a bacterial UDP-xylose synthase, and UDP-xylose 4-epimerase
por: Gu, Xiaogang, et al.
Publicado: (2011)

Catalytic mechanism of human UDP-glucose 6-dehydrogenase: in situ proton NMR studies reveal that the C-5 hydrogen of UDP-glucose is not exchanged with bulk water during the enzymatic reaction
por: Eixelsberger, Thomas, et al.
Publicado: (2012)

UDP-xylose and UDP-galactose synthesis in Trichomonas vaginalis
por: Rosenberger, Andrea F.N., et al.
Publicado: (2012)

Mechanistic characterization of UDP‐glucuronic acid 4‐epimerase
por: Borg, Annika J. E., et al.
Publicado: (2020)

Synthesis of UDP-apiose in Bacteria: The marine phototroph Geminicoccus roseus and the plant pathogen Xanthomonas pisi
por: Smith, James Amor, et al.
Publicado: (2017)

Three UDP-xylose transporters participate in xylan biosynthesis by conveying cytosolic UDP-xylose into the Golgi lumen in Arabidopsis
por: Zhao, Xianhai, et al.
Publicado: (2018)

Facile and Stereo-Selective Synthesis of UDP-α-D-xylose and UDP-β-L-arabinose Using UDP-Sugar Pyrophosphorylase
por: Wang, JiaJia, et al.
Publicado: (2018)

Enzymatic Redox Cascade for One-Pot Synthesis of Uridine 5′-Diphosphate Xylose from Uridine 5′-Diphosphate Glucose
por: Eixelsberger, Thomas, et al.
Publicado: (2014)

Structure and Mechanism of Human UDP-glucose 6-Dehydrogenase
por: Egger, Sigrid, et al.
Publicado: (2011)

Identification of UDP-rhamnosyltransferases and UDP-galactosyltransferase involved in flavonol glycosylation in Morella rubra
por: Ren, Chuanhong, et al.
Publicado: (2022)

UDP-Galactose 4′-Epimerase Activities toward UDP-Gal and UDP-GalNAc Play Different Roles in the Development of Drosophila melanogaster
por: Daenzer, Jennifer M. I., et al.
Publicado: (2012)

UDP-sugar pyrophosphorylase is essential for arabinose and xylose recycling, and is required during vegetative and reproductive growth in Arabidopsis
por: Geserick, Claudia, et al.
Publicado: (2013)

Synthesis of Isorhamnetin-3-O-Rhamnoside by a Three-Enzyme (Rhamnosyltransferase, Glycine Max Sucrose Synthase, UDP-Rhamnose Synthase) Cascade Using a UDP-Rhamnose Regeneration System
por: Chen, Anna, et al.
Publicado: (2019)

Mutagenesis of UDP‐xylose epimerase and xylan arabinosyl‐transferase decreases arabinose content and improves saccharification of rice straw
por: Chen, Chen, et al.
Publicado: (2021)

UDP calzado, Acatlán, Veracruz
por: Ramírez Vázquez, Cindy Berenice
Publicado: (2014)

Controllable Iterative β-Glucosylation from UDP-Glucose by Bacillus cereus Glycosyltransferase GT1: Application for the Synthesis of Disaccharide-Modified Xenobiotics
por: Jung, Jihye, et al.
Publicado: (2021)

Determination of UDP-Glucose and UDP-Galactose in Maize by Hydrophilic Interaction Liquid Chromatography and Tandem Mass Spectrometry
por: Lan, Chen, et al.
Publicado: (2022)

UDP-sulfoquinovose formation by Sulfolobus acidocaldarius
por: Zolghadr, Behnam, et al.
Publicado: (2015)

Depletion of UDP-Glucose and UDP-Galactose Using a Degron System Leads to Growth Cessation of Leishmania major
por: Damerow, Sebastian, et al.
Publicado: (2015)

New steps in mucilage biosynthesis revealed by analysis of the transcriptome of the UDP-rhamnose/UDP-galactose transporter 2 mutant
por: Parra-Rojas, Juan Pablo, et al.
Publicado: (2019)

Structural and Kinetic Evidence That Catalytic Reaction of Human UDP-glucose 6-Dehydrogenase Involves Covalent Thiohemiacetal and Thioester Enzyme Intermediates
por: Egger, Sigrid, et al.
Publicado: (2012)

Correction: Depletion of UDP-Glucose and UDP-Galactose Using a Degron System Leads to Growth Cessation of Leishmania major
por: Damerow, Sebastian, et al.
Publicado: (2016)

The UDP-glucosyltransferase multigene family in Bombyx mori
por: Huang, Fei-Fei, et al.
Publicado: (2008)

Molecular characteristics of plant UDP-arabinopyranose mutases
por: Saqib, Anam, et al.
Publicado: (2019)

Cloning, Expression and Characterization of UDP-Glucose Dehydrogenases
por: Couto, Márcia R., et al.
Publicado: (2021)

UDP-glucose, cereblon-dependent proinsulin degrader
por: Cho, Jaeyong, et al.
Publicado: (2022)

Structure-function and engineering of plant UDP-glycosyltransferase
por: Wang, Mengya, et al.
Publicado: (2023)

Correlation of Apiose Levels and Growth Rates in Duckweeds
por: Pagliuso, Débora, et al.
Publicado: (2018)

Enzymatic C4‐Epimerization of UDP‐Glucuronic Acid: Precisely Steered Rotation of a Transient 4‐Keto Intermediate for an Inverted Reaction without Decarboxylation
por: Borg, Annika J. E., et al.
Publicado: (2022)

Arabidopsis MAP-Kinase 3 Phosphorylates UDP-Glucose Dehydrogenase: a Key Enzyme Providing UDP-Sugar for Cell Wall Biosynthesis
por: Kohlberger, Michael, et al.
Publicado: (2018)

Immobilization of the Highly Active UDP-Glucose Pyrophosphorylase From Thermocrispum agreste Provides a Highly Efficient Biocatalyst for the Production of UDP-Glucose
por: Kumpf, Antje, et al.
Publicado: (2020)

Solvent Engineering for Nonpolar Substrate Glycosylation Catalyzed by the UDP-Glucose-Dependent Glycosyltransferase UGT71E5: Intensification of the Synthesis of 15-Hydroxy Cinmethylin β-d-Glucoside
por: Jung, Jihye, et al.
Publicado: (2023)

Structural Basis of Cooperativity in Human UDP-Glucose Dehydrogenase
por: Rajakannan, Venkatachalam, et al.
Publicado: (2011)

Regulation of Sulfotransferase and UDP-Glucuronosyltransferase Gene Expression by the PPARs
por: Runge-Morris, Melissa, et al.
Publicado: (2009)

Structure and Protein–Protein Interactions of Human UDP-Glucuronosyltransferases
por: Fujiwara, Ryoichi, et al.
Publicado: (2016)

UDP-Glucose: A Potential Signaling Molecule in Plants?
por: Janse van Rensburg, Henry Christopher, et al.
Publicado: (2018)

SpainUDP: The Spanish Undiagnosed Rare Diseases Program
por: López-Martín, Estrella, et al.
Publicado: (2018)

UDP-glucuronosyltransferases and biochemical recurrence in prostate cancer progression
por: Grant, Delores J., et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_vfifl0rdl7uc8rrepg7kdliof6