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The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

[Image: see text] A ferraquinone–ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine...

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Detalles Bibliográficos
Autores principales: Dauth, Alexander, Gellrich, Urs, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5330656/
https://www.ncbi.nlm.nih.gov/pubmed/28141925
http://dx.doi.org/10.1021/jacs.6b13050