The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity

[Image: see text] A ferraquinone–ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine...

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Autores principales: Dauth, Alexander, Gellrich, Urs, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5330656/
https://www.ncbi.nlm.nih.gov/pubmed/28141925
http://dx.doi.org/10.1021/jacs.6b13050
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author Dauth, Alexander
Gellrich, Urs
Diskin-Posner, Yael
Ben-David, Yehoshoa
Milstein, David
author_facet Dauth, Alexander
Gellrich, Urs
Diskin-Posner, Yael
Ben-David, Yehoshoa
Milstein, David
author_sort Dauth, Alexander
collection PubMed
description [Image: see text] A ferraquinone–ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine. Likewise, dehydrogenation of alcohols was achieved through 1,6 metal–ligand cooperation.
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spelling pubmed-53306562017-03-02 The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity Dauth, Alexander Gellrich, Urs Diskin-Posner, Yael Ben-David, Yehoshoa Milstein, David J Am Chem Soc [Image: see text] A ferraquinone–ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine. Likewise, dehydrogenation of alcohols was achieved through 1,6 metal–ligand cooperation. American Chemical Society 2017-01-31 2017-02-22 /pmc/articles/PMC5330656/ /pubmed/28141925 http://dx.doi.org/10.1021/jacs.6b13050 Text en Copyright © 2017 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Dauth, Alexander
Gellrich, Urs
Diskin-Posner, Yael
Ben-David, Yehoshoa
Milstein, David
The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity
title The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity
title_full The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity
title_fullStr The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity
title_full_unstemmed The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity
title_short The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity
title_sort the ferraquinone–ferrahydroquinone couple: combining quinonic and metal-based reactivity
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5330656/
https://www.ncbi.nlm.nih.gov/pubmed/28141925
http://dx.doi.org/10.1021/jacs.6b13050
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