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The Ferraquinone–Ferrahydroquinone Couple: Combining Quinonic and Metal-Based Reactivity
[Image: see text] A ferraquinone–ferrahydroquinone organometallic redox couple was prepared and characterized. Intricate cooperativity of the metal was observed with different positions on the ligand. This allowed cooperative activation of small molecules like molecular hydrogen, oxygen, and bromine...
Autores principales: | Dauth, Alexander, Gellrich, Urs, Diskin-Posner, Yael, Ben-David, Yehoshoa, Milstein, David |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2017
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5330656/ https://www.ncbi.nlm.nih.gov/pubmed/28141925 http://dx.doi.org/10.1021/jacs.6b13050 |
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