Enhancing the catalytic activity of hydronium ions through constrained environments

The dehydration of alcohols is involved in many organic conversions but has to overcome high free-energy barriers in water. Here we demonstrate that hydronium ions confined in the nanopores of zeolite HBEA catalyse aqueous phase dehydration of cyclohexanol at a rate significantly higher than hydroni...

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Detalles Bibliográficos
Autores principales: Liu, Yuanshuai, Vjunov, Aleksei, Shi, Hui, Eckstein, Sebastian, Camaioni, Donald M., Mei, Donghai, Baráth, Eszter, Lercher, Johannes A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5337972/
https://www.ncbi.nlm.nih.gov/pubmed/28252021
http://dx.doi.org/10.1038/ncomms14113

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5337972/
https://www.ncbi.nlm.nih.gov/pubmed/28252021
http://dx.doi.org/10.1038/ncomms14113

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