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When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides
[Image: see text] The direct introduction of the valuable SCF(3) moiety into organic molecules has received considerable attention. While it can be achieved successfully for aryl chlorides under catalysis with Ni(0)(cod)(2) and dppf, this report investigates the Ni-catalyzed functionalization of the...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American
Chemical Society
2017
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5339856/ https://www.ncbi.nlm.nih.gov/pubmed/28286695 http://dx.doi.org/10.1021/acscatal.6b03344 |