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Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes

Metal carbenes are often proposed as reactive intermediates in the late transition metal-catalysed transformations of alkynes. Owing to their high reactivity, however, isolation and structural characterization of metal carbene intermediates in these transformations has remained unknown. Herein, we r...

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Detalles Bibliográficos
Autores principales: Wang, Jiwei, Cao, Xiaoming, Lv, Shichang, Zhang, Caiyun, Xu, Sheng, Shi, Min, Zhang, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5343500/
https://www.ncbi.nlm.nih.gov/pubmed/28262737
http://dx.doi.org/10.1038/ncomms14625