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Synthesis and structures of gold and copper carbene intermediates in catalytic amination of alkynes
Metal carbenes are often proposed as reactive intermediates in the late transition metal-catalysed transformations of alkynes. Owing to their high reactivity, however, isolation and structural characterization of metal carbene intermediates in these transformations has remained unknown. Herein, we r...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5343500/ https://www.ncbi.nlm.nih.gov/pubmed/28262737 http://dx.doi.org/10.1038/ncomms14625 |