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Formation of novel transition metal hydride complexes with ninefold hydrogen coordination

Ninefold coordination of hydrogen is very rare, and has been observed in two different hydride complexes comprising rhenium and technetium. Herein, based on a theoretical/experimental approach, we present evidence for the formation of ninefold H- coordination hydride complexes of molybdenum ([MoH(9)...

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Detalles Bibliográficos
Autores principales: Takagi, Shigeyuki, Iijima, Yuki, Sato, Toyoto, Saitoh, Hiroyuki, Ikeda, Kazutaka, Otomo, Toshiya, Miwa, Kazutoshi, Ikeshoji, Tamio, Orimo, Shin-ichi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347150/
https://www.ncbi.nlm.nih.gov/pubmed/28287143
http://dx.doi.org/10.1038/srep44253