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Formation of novel transition metal hydride complexes with ninefold hydrogen coordination
Ninefold coordination of hydrogen is very rare, and has been observed in two different hydride complexes comprising rhenium and technetium. Herein, based on a theoretical/experimental approach, we present evidence for the formation of ninefold H- coordination hydride complexes of molybdenum ([MoH(9)...
Autores principales: | Takagi, Shigeyuki, Iijima, Yuki, Sato, Toyoto, Saitoh, Hiroyuki, Ikeda, Kazutaka, Otomo, Toshiya, Miwa, Kazutoshi, Ikeshoji, Tamio, Orimo, Shin-ichi |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347150/ https://www.ncbi.nlm.nih.gov/pubmed/28287143 http://dx.doi.org/10.1038/srep44253 |
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