Stereodivergent Olefination of Enantioenriched Boronic Esters

A stereodivergent coupling reaction between vinyl halides and boronic esters is described. This coupling process proceeds without a transition‐metal catalyst, instead proceeding by electrophilic selenation or iodination of a vinyl boronate complex followed by stereospecific syn or anti elimination....

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Detalles Bibliográficos
Autores principales: Armstrong, Roly J., García‐Ruiz, Cristina, Myers, Eddie L., Aggarwal, Varinder K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2016
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347846/
https://www.ncbi.nlm.nih.gov/pubmed/27958668
http://dx.doi.org/10.1002/anie.201610387

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347846/
https://www.ncbi.nlm.nih.gov/pubmed/27958668
http://dx.doi.org/10.1002/anie.201610387

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