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Palladium(II)‐Catalysed Aminocarbonylation of Terminal Alkynes for the Synthesis of 2‐Ynamides: Addressing the Challenges of Solvents and Gas Mixtures

2‐Ynamides can be synthesised through Pd(II) catalysed oxidative carbonylation, utilising low catalyst loadings. A variety of alkynes and amines can be used to afford 2‐ynamides in high yields, whilst overcoming the drawbacks associated with previous oxidative methods, which rely on dangerous solven...

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Detalles Bibliográficos
Autores principales: Hughes, N. Louise, Brown, Clare L., Irwin, Andrew A., Cao, Qun, Muldoon, Mark J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5347853/
https://www.ncbi.nlm.nih.gov/pubmed/27906507
http://dx.doi.org/10.1002/cssc.201601601