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Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C–H activation
Since our initial report in 1976, the oxygen rebound mechanism has become the consensus mechanistic feature for an expanding variety of enzymatic C–H functionalization reactions and small molecule biomimetic catalysts. For both the biotransformations and models, an initial hydrogen atom abstraction...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Springer Berlin Heidelberg
2016
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5350257/ https://www.ncbi.nlm.nih.gov/pubmed/27909920 http://dx.doi.org/10.1007/s00775-016-1414-3 |