Sequential catalysis: exploiting a single rhodium(i) catalyst to promote an alkyne hydroacylation–aryl boronic acid conjugate addition sequence

We demonstrate that a single Rh(i) complex can promote two mechanistically distinct C–C bond-forming reactions – alkyne hydroacylation and aryl boronic acid conjugate addition – to deliver substituted ketone products from the controlled assembly of three readily available fragments. This is a rare e...

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Detalles Bibliográficos
Autores principales: Fernández, Maitane, Castaing, Matthias, Willis, Michael C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5351800/
https://www.ncbi.nlm.nih.gov/pubmed/28451201
http://dx.doi.org/10.1039/c6sc03066a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5351800/
https://www.ncbi.nlm.nih.gov/pubmed/28451201
http://dx.doi.org/10.1039/c6sc03066a

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