Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C–H activation

The diastereoselective coupling of O-substituted arylhydroxamates and cyclopropenes mediated by Rh(iii) catalysis was successfully developed. Through ligand development, the diastereoselectivity of this reaction was improved using a heptamethylindenyl (Ind*) ligand, which has been rationalized using...

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Detalles Bibliográficos
Autores principales: Semakul, Natthawat, Jackson, Kelvin E., Paton, Robert S., Rovis, Tomislav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5354047/
https://www.ncbi.nlm.nih.gov/pubmed/28451239
http://dx.doi.org/10.1039/c6sc02587k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5354047/
https://www.ncbi.nlm.nih.gov/pubmed/28451239
http://dx.doi.org/10.1039/c6sc02587k

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