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Porphyrin–Polyyne [3]- and [5]Rotaxanes
[Image: see text] Porphyrin–polyyne [3]- and [5]rotaxanes have been synthesized by condensing aldehyde–rotaxanes with pyrrole or dipyrromethane. The crystal structure of a [3]rotaxane shows that the macrocycles adopt compact conformations, holding the hexaynes near the porphyrin core, and that the p...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5354311/ https://www.ncbi.nlm.nih.gov/pubmed/28054784 http://dx.doi.org/10.1021/acs.orglett.6b03528 |