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Dynamic propeller conformation for the unprecedentedly high degree of chiral amplification of supramolecular helices

An unprecedentedly high degree of chiral amplification of supramolecular helices in a sergeants and soldiers system was realized using a propeller-shaped molecule, triphenylamine (TPA), as the monomer. One sergeant controlled the handedness of 500 soldiers in supramolecular helices. We further demon...

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Detalles Bibliográficos
Autores principales: Kim, Taehoon, Mori, Tadashi, Aida, Takuzo, Miyajima, Daigo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5355865/
https://www.ncbi.nlm.nih.gov/pubmed/28451111
http://dx.doi.org/10.1039/c6sc02814d