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Solvent responsive catalyst improves NMR sensitivity via efficient magnetisation transfer

A bidentate iridium carbene complex, Ir(κC,O-L(1))(COD), has been synthesised which contains a strongly electron donating carbene ligand that is functionalised by a cis-spanning phenolate group. This complex acts as a precursor to effective magnetisation transfer catalysts which form after reaction...

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Detalles Bibliográficos
Autores principales: Ruddlesden, Amy J., Duckett, Simon B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5358499/
https://www.ncbi.nlm.nih.gov/pubmed/27311751
http://dx.doi.org/10.1039/c6cc03185d