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Solvent responsive catalyst improves NMR sensitivity via efficient magnetisation transfer
A bidentate iridium carbene complex, Ir(κC,O-L(1))(COD), has been synthesised which contains a strongly electron donating carbene ligand that is functionalised by a cis-spanning phenolate group. This complex acts as a precursor to effective magnetisation transfer catalysts which form after reaction...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5358499/ https://www.ncbi.nlm.nih.gov/pubmed/27311751 http://dx.doi.org/10.1039/c6cc03185d |