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Tuning of Exchange Coupling and Switchable Magnetization Dynamics by Displacing the Bridging Ligands Observed in Two Dimeric Manganese(III) Compounds
Two Mn(III)-based dimers, [Mn(2)(bpad)(2)(CH(3)O)(4)](n) (1) and [Mn(2)(bpad)(2)(pa)(2)](n)·2H(2)O (2) (Hbpad = N(3)-benzoylpyridine-2-carboxamidrazone, H(2)pa = phthalic acid), have been assembled from a tridentate Schiff-base chelator and various anionic coligands. Noteworthily, compound 1 could b...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5359551/ https://www.ncbi.nlm.nih.gov/pubmed/28322305 http://dx.doi.org/10.1038/srep44982 |