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Tuning of Exchange Coupling and Switchable Magnetization Dynamics by Displacing the Bridging Ligands Observed in Two Dimeric Manganese(III) Compounds

Two Mn(III)-based dimers, [Mn(2)(bpad)(2)(CH(3)O)(4)](n) (1) and [Mn(2)(bpad)(2)(pa)(2)](n)·2H(2)O (2) (Hbpad = N(3)-benzoylpyridine-2-carboxamidrazone, H(2)pa = phthalic acid), have been assembled from a tridentate Schiff-base chelator and various anionic coligands. Noteworthily, compound 1 could b...

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Detalles Bibliográficos
Autores principales: Liu, Xiang-Yu, Cen, Pei-Pei, Wu, Li-Zhou, Li, Fei-Fei, Song, Wei-Ming, Xie, Gang, Chen, San-Ping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5359551/
https://www.ncbi.nlm.nih.gov/pubmed/28322305
http://dx.doi.org/10.1038/srep44982