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Electronic nature of zwitterionic alkali metal methanides, silanides and germanides – a combined experimental and computational approach

Zwitterionic group 14 complexes of the alkali metals of formula [C(SiMe(2)OCH(2)CH(2)OMe)(3)M], (M-1), [Si(SiMe(2)OCH(2)CH(2)OMe)(3)M], (M-2), [Ge(SiMe(2)OCH(2)CH(2)OMe)(3)M], (M-3), where M = Li, Na or K, have been prepared, structurally characterized and their electronic nature was investigated by...

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Detalles Bibliográficos
Autores principales: Li, H., Aquino, A. J. A., Cordes, D. B., Hase, W. L., Krempner, C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5360169/
https://www.ncbi.nlm.nih.gov/pubmed/28451273
http://dx.doi.org/10.1039/c6sc02390h