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Fluorinated antimony(v) derivatives: strong Lewis acidic properties and application to the complexation of formaldehyde in aqueous solutions

As part of our ongoing studies of water tolerant Lewis acids, we have synthesized and investigated the properties of Sb(C(6)F(5))(3)(O(2)C(6)Cl(4)), a fluorinated stiborane whose Lewis acidity approaches that of B(C(6)F(5))(3). While chloroform solutions of this Lewis acid can be kept open to air or...

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Detalles Bibliográficos
Autores principales: Tofan, Daniel, Gabbaï, François P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5363782/
https://www.ncbi.nlm.nih.gov/pubmed/28451122
http://dx.doi.org/10.1039/c6sc02558g