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Chemical control of the viscoelastic properties of vinylogous urethane vitrimers

Vinylogous urethane based vitrimers are polymer networks that have the intrinsic property to undergo network rearrangements, stress relaxation and viscoelastic flow, mediated by rapid addition/elimination reactions of free chain end amines. Here we show that the covalent exchange kinetics significan...

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Detalles Bibliográficos
Autores principales: Denissen, Wim, Droesbeke, Martijn, Nicolaÿ, Renaud, Leibler, Ludwik, Winne, Johan M., Du Prez, Filip E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364391/
https://www.ncbi.nlm.nih.gov/pubmed/28317893
http://dx.doi.org/10.1038/ncomms14857