Catalytic N(2)-to-NH(3) Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET

[Image: see text] We have recently reported on several Fe catalysts for N(2)-to-NH(3) conversion that operate at low temperature (−78 °C) and atmospheric pressure while relying on a very strong reductant (KC(8)) and acid ([H(OEt(2))(2)][BAr(F)(4)]). Here we show that our original catalyst system, P(...

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Detalles Bibliográficos
Autores principales: Chalkley, Matthew J., Del Castillo, Trevor J., Matson, Benjamin D., Roddy, Joseph P., Peters, Jonas C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2017
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364448/
https://www.ncbi.nlm.nih.gov/pubmed/28386599
http://dx.doi.org/10.1021/acscentsci.7b00014

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364448/
https://www.ncbi.nlm.nih.gov/pubmed/28386599
http://dx.doi.org/10.1021/acscentsci.7b00014

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