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Catalytic N(2)-to-NH(3) Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET
[Image: see text] We have recently reported on several Fe catalysts for N(2)-to-NH(3) conversion that operate at low temperature (−78 °C) and atmospheric pressure while relying on a very strong reductant (KC(8)) and acid ([H(OEt(2))(2)][BAr(F)(4)]). Here we show that our original catalyst system, P(...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364448/ https://www.ncbi.nlm.nih.gov/pubmed/28386599 http://dx.doi.org/10.1021/acscentsci.7b00014 |