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Highly Enantioselective Oxidation of Nonactivated Aliphatic C–H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes
[Image: see text] Monosubstituted cycloalkanes undergo regio- and enantioselective aliphatic C–H oxidation with H(2)O(2) catalyzed by biologically inspired manganese catalysts. The reaction furnishes the corresponding ketones resulting from oxidation at C3 and C4 methylenic sites (K(3) and K(4), res...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2017
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364455/ https://www.ncbi.nlm.nih.gov/pubmed/28386597 http://dx.doi.org/10.1021/acscentsci.6b00368 |