A full set of iridium(iv) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties

We introduce and characterize the complete set of possible isomers of Ir(IV)(pyalk)(2)Cl(2) (pyalk = 2-(pyridin-2-yl)propan-2-oate), providing valuable insights on the properties of Ir(iv) species. The pyridine alkoxide ligand strongly stabilizes high oxidation states, essential to accessing the cat...

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Detalles Bibliográficos
Autores principales: Shopov, Dimitar Y., Rudshteyn, Benjamin, Campos, Jesús, Vinyard, David J., Batista, Victor S., Brudvig, Gary W., Crabtree, Robert H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364517/
https://www.ncbi.nlm.nih.gov/pubmed/28451293
http://dx.doi.org/10.1039/c6sc03758e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364517/
https://www.ncbi.nlm.nih.gov/pubmed/28451293
http://dx.doi.org/10.1039/c6sc03758e

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