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A full set of iridium(iv) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties
We introduce and characterize the complete set of possible isomers of Ir(IV)(pyalk)(2)Cl(2) (pyalk = 2-(pyridin-2-yl)propan-2-oate), providing valuable insights on the properties of Ir(iv) species. The pyridine alkoxide ligand strongly stabilizes high oxidation states, essential to accessing the cat...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364517/ https://www.ncbi.nlm.nih.gov/pubmed/28451293 http://dx.doi.org/10.1039/c6sc03758e |