Photoredox radical conjugate addition of dithiane-2-carboxylate promoted by an iridium(iii) phenyl-tetrazole complex: a formal radical methylation of Michael acceptors

A readily accessible iridium(iii) phenyl-tetrazole complex ([Ir(ptrz)(2)(tBu-bpy)](+), 2; Hptrz = 2-methyl-5-phenyl-tetrazole; tBu-bpy = 4,4′-di-tert-butyl-2,2′-bipyridine) is shown to be a versatile catalyst for a new photocatalytic Michael reaction. Under light irradiation in the presence of 2, a...

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Detalles Bibliográficos
Autores principales: Gualandi, Andrea, Matteucci, Elia, Monti, Filippo, Baschieri, Andrea, Armaroli, Nicola, Sambri, Letizia, Cozzi, Pier Giorgio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364518/
https://www.ncbi.nlm.nih.gov/pubmed/28451291
http://dx.doi.org/10.1039/c6sc03374a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364518/
https://www.ncbi.nlm.nih.gov/pubmed/28451291
http://dx.doi.org/10.1039/c6sc03374a

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