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Photoredox radical conjugate addition of dithiane-2-carboxylate promoted by an iridium(iii) phenyl-tetrazole complex: a formal radical methylation of Michael acceptors
A readily accessible iridium(iii) phenyl-tetrazole complex ([Ir(ptrz)(2)(tBu-bpy)](+), 2; Hptrz = 2-methyl-5-phenyl-tetrazole; tBu-bpy = 4,4′-di-tert-butyl-2,2′-bipyridine) is shown to be a versatile catalyst for a new photocatalytic Michael reaction. Under light irradiation in the presence of 2, a...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2017
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5364518/ https://www.ncbi.nlm.nih.gov/pubmed/28451291 http://dx.doi.org/10.1039/c6sc03374a |