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Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)

A donor–acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into mole...

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Detalles Bibliográficos
Autores principales: Swarnakar, Anindya K., Hering-Junghans, Christian, Ferguson, Michael J., McDonald, Robert, Rivard, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5365008/
https://www.ncbi.nlm.nih.gov/pubmed/28451338
http://dx.doi.org/10.1039/c6sc04893e