Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)

A donor–acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into mole...

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Detalles Bibliográficos
Autores principales: Swarnakar, Anindya K., Hering-Junghans, Christian, Ferguson, Michael J., McDonald, Robert, Rivard, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5365008/
https://www.ncbi.nlm.nih.gov/pubmed/28451338
http://dx.doi.org/10.1039/c6sc04893e
Descripción
Sumario:A donor–acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into molecular complexes of BN. This work provides added impetus for the development of molecular precursors that can release bulk boron nitride (a desirable insulator and thermal conductor) under mild conditions, and from solution.

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