Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)

A donor–acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into mole...

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Autores principales: Swarnakar, Anindya K., Hering-Junghans, Christian, Ferguson, Michael J., McDonald, Robert, Rivard, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2017
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5365008/
https://www.ncbi.nlm.nih.gov/pubmed/28451338
http://dx.doi.org/10.1039/c6sc04893e
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author Swarnakar, Anindya K.
Hering-Junghans, Christian
Ferguson, Michael J.
McDonald, Robert
Rivard, Eric
author_facet Swarnakar, Anindya K.
Hering-Junghans, Christian
Ferguson, Michael J.
McDonald, Robert
Rivard, Eric
author_sort Swarnakar, Anindya K.
collection PubMed
description A donor–acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into molecular complexes of BN. This work provides added impetus for the development of molecular precursors that can release bulk boron nitride (a desirable insulator and thermal conductor) under mild conditions, and from solution.
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spelling pubmed-53650082017-04-27 Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+) Swarnakar, Anindya K. Hering-Junghans, Christian Ferguson, Michael J. McDonald, Robert Rivard, Eric Chem Sci Chemistry A donor–acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into molecular complexes of BN. This work provides added impetus for the development of molecular precursors that can release bulk boron nitride (a desirable insulator and thermal conductor) under mild conditions, and from solution. Royal Society of Chemistry 2017-03-01 2016-12-19 /pmc/articles/PMC5365008/ /pubmed/28451338 http://dx.doi.org/10.1039/c6sc04893e Text en This journal is © The Royal Society of Chemistry 2017 https://creativecommons.org/licenses/by-nc/3.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial 3.0 Unported License (http://creativecommons.org/licenses/by-nc/3.0/ (https://creativecommons.org/licenses/by-nc/3.0/) ) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Swarnakar, Anindya K.
Hering-Junghans, Christian
Ferguson, Michael J.
McDonald, Robert
Rivard, Eric
Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)
title Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)
title_full Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)
title_fullStr Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)
title_full_unstemmed Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)
title_short Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)
title_sort reactivity of a coordinated inorganic acetylene unit, hbnh, and the azidoborane cation [hb(n(3))](+)
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5365008/
https://www.ncbi.nlm.nih.gov/pubmed/28451338
http://dx.doi.org/10.1039/c6sc04893e
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