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Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N(3))](+)
A donor–acceptor complex of HBNH was prepared via thermolysis of a carbene-stabilized azidoborane. The reactivity of the fundamentally important HBNH unit (inorganic alkyne analogue) was explored in detail, including attempts to convert this species and related hydrido(azido)borane cations into mole...
Autores principales: | Swarnakar, Anindya K., Hering-Junghans, Christian, Ferguson, Michael J., McDonald, Robert, Rivard, Eric |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5365008/ https://www.ncbi.nlm.nih.gov/pubmed/28451338 http://dx.doi.org/10.1039/c6sc04893e |
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